Hello Leo,
I am not 100% sure and cannot test that, but I would give a try to stop just the DDF, not the member and try it with a MODIFY DDF as Mike told you. Did you try it?
I did something similar with the ALIAS at a Data Sharing, and for being able to do it I had to STOP the ALIAS first. These are my notes when I remove the nonsecure port from an alias and letting just the Secure one:
1. DB2J DIS DDF DETAIL
2. DB2J modify ddf alias(D2TALIA1) STOP
3. DB2J modify ddf alias(D2TALIA1) NPORT
4. DB2J modify ddf alias(D2TALIA1) START
5. DB2J DIS DDF DETAIL
And this screenshot explaning to myself why I had to stop the ALIAS

DSNL313I - IBM Documentation
I know you were not asking this but just in case it helps.
Thanks,