Dear Aldrin
I did a Google search with "ibm i maximum spooled files" and found that this article by the expert Dawn May should give you the answer: Get Notified When Nearing the Maximum Number of Spooled Files at https://techchannel.com/i-can-blog/get-notified-when-nearing-the-maximum-number-of-spooled-files/. There are also several hot links in the article for more relevant information.
These two Technotes are also useful:
IBM i System Limit for Maximum Number of Spooled Files at https://www.ibm.com/support/pages/ibm-i-system-limit-maximum-number-spooled-files.
Alerts for IBM i System Limits at https://www.ibm.com/support/pages/alerts-ibm-i-system-limits. Notice that you can change the % threshold for alert notification with simple SQL statement to the system's global variables.