Possibly related to KI DT437589.
Are you using Chrome v136 or higher?
In Chrome v136, they implemented a security measure that no longer allows Selenium to work with the default profile folder.
In order to use the logged-in user's profile, you must create another profile using a folder other than the default one.
This functionality (to allow the user provides a custom profile folder) was added to IBM RPA 23.0.20 (FP 003) and v 30.0.0.
However, if you open a ticket, the support team can provide you with a custom build based on version 23.0.20 (FP 002) - current latest version.
When the support team provides you with the custom build, they will send you the step-by-step instructions for configuring the user profile with the new folder for use in IBM RPA.