From what I can tell there isn't a VS Code side setting for this. Per the Z Open Editor docs, the RCE client gets its 3270 details from the RSE API server, and RCE_PORT, RCE_LUNAME, RCE_ENABLE and RCE_SECURITY are all host side settings in the RSE API config (rseapi.env). Your RSE API profile in Zowe Explorer only controls how VS Code reaches RSE API itself. So the practical path is having your RSE API admin set RCE_PORT to the right TN3270 port and recycle RSE API. If you really need a per user override, I'd open an enhancement at github.com/IBM/zopeneditor-about so the Z Open Editor team sees it. Happy to be corrected if someone from the IDz team knows a setting I missed.
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Daniel Barraza
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