Ok.. I'll try to make it simple. So dont take this as definition :-)
Work Load management - How you distribute the load and manage it.
High Availability - How muchtime your solution/application is available.
Say you have an application. You define that this application must be available 364days in a year. That is application's availability. How do you achieve this? Create a failover system, backup plan, monitoring etc ..
Now you need the response time to be 1-2seconds. This is not covered in above statement of availability. How do you achieve this then? you take multiple servers and distribute the incoming load among them to maintain the response time you need.
cheers