If the web service is not invoked successfully, you will get the error message from error log. Or you can use try/catch block to catch the exception when the service is failed and then do some customized handling, for example log it and send notification mail.
And, the handling method above still can’t guarantee you control all the phases of service invoke, maybe the request is not received because some network issue, the client will get an error, and you get nothing.
#webMethods#Integration-Server-and-ESB