You can do this by using a computed category. Here is an example using the employee data.sav file shipped with Statistics. If you have a total in the table, you could use that as the denominator.
CTABLES
/PCOMPUTE &cat1 = EXPR(['f'] / (['f'] + ['m']) * 100)
/PPROPERTIES &cat1 LABEL = " percent female" FORMAT=MEAN PCT40.0 HIDESOURCECATS=NO
/TABLE gender > (salary [MEAN] + salbegin [MEAN]) BY minority
/CATEGORIES VARIABLES=gender ['f', 'm', &cat1, OTHERNM] EMPTY=INCLUDE
/CATEGORIES VARIABLES=minority ORDER=A KEY=VALUE EMPTY=INCLUDE MISSING=EXCLUDE.
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